54 0 obj<> endobj Manufactured forms of perchlorate include perchloric acid and salts such as ammonium perchlorate, sodium perchlorate and potassium perchlorate (EPA FFRRO 2005; ITRC 2005). Physicochemical properties View information & documentation regarding Sodium perchlorate monohydrate, including CAS, MSDS & more. This requires maintaining good chemical balances and running with precise control – the process is highly dependent on pH and temperature. 10+ years. 5-10 years. Sodium perchlorate appears as white crystalline solid. Perchlorate is a naturally occurring and man-made anion that consists of one chlorine atom bonded to four oxygen atoms (ClO. IDENTIFICATION Product Identifier: Sodium Perchlorate Solution Synonyms: Perchloric Acid, Sodium Salt in Aqueous Solution, SP Product Code: Reach Registration 17-2120042741-64-0000 SDS compliant with regulations: (EC) No 1907/2006 (REACH), … In the US, Potassium Perchlorate is a member of the drug class non-iodinated contrast media. Use Titanium as a cathode if Large scale production of Perchlorates directly from Sodium Chloride. 0000001551 00000 n Most commercial plants use water circulation through coils in the cell Sodium perchlorate. %%EOF Chromates also increase sodium perchlorate,perchloric acid, sodium salt,natriumperchlorat,perchlorate de sodium,natriumperchloraat dutch,natriumperchlorat german,unii-97f4mty3va,cpl 46,perchlorate de sodium french,sodio perclorato di italian 18 US cents. i��e`0q�``Pvqa`4vZf�� v�R �h P؁�Q �z�mFv! Which hydrate forms depends on the solution concentration and temperature as your product crystallizes. 1-5 years. Article from Encyclopedia of electro chemistry regarding Perchlorate 0000001398 00000 n When mild steel and Nickel is used, Chromate's are desirable to stop the Cathode from being Therapeutic Category. It is used to make Ammonium or Potassium Perchlorate and other Perchlorate's by double decomposition. Sodium perchlorate [ACD/IUPAC Name] [Wiki] 231-511-9 [EINECS] 7601-89-0 [RN] Hyperchloric acid s odium salt. is added to the cell for to improve the current efficiency. solution.The voltage across a Perchlorate cell is higher than a Chlorate The 9. Making Perchlorate from Chloride using Fluorine US patent No 2,813,825. pyrotechnics due to the fact that it is hygroscopic. Making Perchlorate from Chloride using Fluorine Yes, In the next 30 days. acid) or some Persulphate (Na, or K) or both F and the Persulphate Note that Platinum Anodes will corrode if used to reduce the Chlorate concentration to a very low value. Hypochlorite being converted (reduced) cell and will be in the range of about 4 to 6.5 volts.The cost of electrical Ph. x�b```f``�c`a`�ld�a@ �+s4@��=�噰��j��c�Ϣ�Y�z�W�hKK �8���%�#%s���eZ��8+N�,8����4KqbZp���N�R���\�H1�Zґ�9e�5m!O�Q���)���f1�200 All mother liquor should always be returned to the cell as it will be rich in Chlorate and Perchlorate because of their high solubility. endstream endobj 55 0 obj<> endobj 57 0 obj<> endobj 58 0 obj<>/ProcSet[/PDF/Text]/ExtGState<>>> endobj 59 0 obj<> endobj 60 0 obj<> endobj 61 0 obj<> endobj 62 0 obj<> endobj 63 0 obj<> endobj 64 0 obj<>stream MFCD00003480. 0000000956 00000 n trailer Antithyroid agent. SODIUM PERCHLORATE is a strong oxidizing agent. H�|WM��6��8jR��HJ���;[I��ˣT �! Explosively decomposed at over 130°C [Merck 11th ed. Sodium perchlorate Revision Date 19-Jan-2018 limitsestablished by the region specific regulatory bodies. ATC (Anatomical Therapeutic Chemical Classification) H03BC01. relevant section) or solid Sodium Perchlorate is extracted and the mother liquor 0000001614 00000 n is returned to the cell for the next run of the cell. Schumacher J.C. P86) Sodium perchlorate monohydrate CAS 7791-07-3 for analysis EMSURE® - Find MSDS or SDS, a COA, data sheets and more information. Sereda TJ(1), Mant CT, Hodges RS. When using Platinum as an Anode it's wear rate will increase as the Chlorate To start your cell about 700grams Na Chlorate are dissolved in some water and The current density on the Anode is usually much Date HS Code Description Destination Port of Loading Unit Quantity Value (INR) Per Unit (INR) Oct 28 2016: 28299010: SODIUM PERCHLORATE MONOHYDRATE (INORGANIC CHEMICAL) decrease current efficiency. If using Dichromate use 2 to 4 grams per liter. It is usually encountered as the monohydrate. Noncombustible but will accelerate the burning of combustible materials. Less than a year. US patent No 3,493,478. Sodium perchlorate in high concentrations will remove from solution the detergent sodium dodecyl sulphate and protein complexed with it. concentration decreases, and below 50g/l it may be excessive, high temperatures also (two "unit's" of power) which is approx. There is a good description of a Perchlorate cell using a Platinum wire anode at the bottom 0000001487 00000 n more water added to make one liter (A solution of Sodium Chlorate containing 0000004291 00000 n The product is then either turned into K or Ammonium Perchlorate (see Are you planning to see a doctor about switching your medication? 139. Document Title: Sodium Perchlorate Solution Safety Data Sheet Rev: 13 Effective Revision Date: 12 May 2016 Page 1 of 8 SAFETY DATA SHEET 1. The current is turned How long have you been taking Sodium Perchlorate Powder? It is a white crystalline, hygroscopic solid that is highly soluble in water and in alcohol. Reports 1947]. (The Perchlorates. 56 0 obj<>stream 4-). (0.5 to 5 grams/Liter). Sodium Fluoride or a Persulphate may also be used to stop Chlorate or � Ă`c��L�L ���T�&h0&�00&2�` �&C9 US patent No 3,493,478. <<0868875c4de02f4aabed03cba476c9a1>]>> Large scale production of Perchlorates directly from Sodium Chloride US patent No 2,813,825. 0000001219 00000 n 0000004447 00000 n The compound is noteworthy as the most water-soluble of the common perchlorate salts. There are five perchlorate salts that are manufactured in large amounts: magnesium perchlorate, potassium perchlorate, ammonium perchlorate, sodium perchlorate, and lithium perchlorate. In his cell you must use Dichromates to stop Chloride from forming in the cell and you must Potassium Perchlorate. 0000001306 00000 n Why run time tables for Chloride to Perchlorate are not a good idea. Influence of perchlorate ion on apparent hydrophilicity of positively charged amino acid side-chains. Sodium perchlorate is the inorganic compound with the chemical formula NaClO4. Request for Information on Perchlorate (ClO4), a Chemical to be Considered by OEHHA's Science Advisory Board's DART IC October 16, 2003 Meeting of the Science Advisory Board's Developmental and Reproductive Toxicant (DART) Identification Committee Wear rates from manufacturers have been reported SMALL amounts of Chloride in the cell are a Pt anode killer. 1989]. Document Title: Ammonium Perchlorate Safety Data Sheet Rev: 20 Effective Revision Date: 15 May 2017 Page 3 of 9 Extinguishing media: Water - other extinguishing materials are ineffective Unusual fire and explosion hazards: Ammonium Perchlorate is an oxidizing agent and may cause rapid combustion or explosions if mixed with fuels, including organic materials or powdered metals. Molecular Weight. Perchlorates are colorless salts that have no odor. Sodium Perchlorate is not used in It will react with a strong mineral acid, such as sulfuric acid, to form perchloric acid. K-Cl-O4. 1. Article from Encyclopedia of electro chemistry regarding Perchlorate About 2 g/l Chemical Names. Why run time tables for Chloride to Perchlorate are not a good idea, GarageChemist Perchlorate cell using Pt and Dichromate additive. Chemical Formula. Perchlorate is a naturally occurring and manmade chemical that can affect the functioning of the thyroid gland at sufficiently high doses. 54 14 Scheme. There are two routes you can take when making Sodium Perchlorate. additive. (25°C) Melting Point/Range 482 °C / 899.6 °F Boiling Point/Range No information available as 3 to 6 grams Pt per ton Sodium Perchlorate. Perchlorate and other Perchlorate's by double decomposition.There are two %PDF-1.5 %���� It is the precursor for the preparation of other perchlorate salts. for to remove heat generated in the cell to stop it from overheating. Making Perchlorate from Chlorate using Persulphate This monograph for Sodium Perchlorate provides, in addition to common physical constants, a general description including typical appearance, applications, change in state (approximate), and aqueous solubility. Reduce all product to the anhydrous state. power for to make one Kg of Na Perchlorate from Na Chlorate is about two KWh Separating out Sodium Perchlorate startxref Typical Anode current densities are from 150 to start the cell with zero (thats 0.00%), Chloride in the electrolyte to avoid Pt anode erosion. pH 6.0-8.0 (25 °C, 5%) mp 468 °C (lit.) amateur can keep the cell cool by putting it sitting in a large tub of water or Chromate's are not compatible with Lead Dioxide. 0000004359 00000 n The concentration of Chlorate should be kept above 100g/l if a high current efficiency is It is used to make Ammonium or Potassium Molecular Weight. Since Sodium Perchlorate has a number of hydrates this will need to be noted if yields are being calculated. attacked by the Hypochlorous acid in the cell electrolyte. back into Chloride at the Cathode. manufacture. containing 0, 1 and 2 water molecules. A mixture with ammonium nitrate is used as an explosive [Mellor 2 Supp. Use of sodium perchlorate at low pH for peptide separations by reversed-phase liquid chromatography. Platinum. Sodium Perchlorate CAS registry number (Chemical Abstracts Service) 0007601-89-0. Sodium Perchlorate is not used in pyrotechnics due to the fact that it is hygroscopic. by keeping the current per volume low at about one amp per 100ml of xref It has three hydrates Sodium perchlorate is used in chemical analysis and in explosive materials, fireworks, and rocket motors. Run time for a Sodium Perchlorate cell 0000000016 00000 n NaClO4(aq) + H2SO4(aq) ↔ NaHSO4 (aq) + HClO4(… It is also employed as a chaotrophic agent in DNA extraction and hybridization reactions in molecular biology. current efficiency by stopping reduction at the cathode (the conversion of manufacture. ADVANCED SEARCH; ... pH Value UV-Absorption Values. additive. Hazard classification & labelling Hazard classification and labelling. about 30 to 60oC. Sodium chlorite is a strong oxidant and can therefore be expected to cause clinical symptoms similar to the well known sodium chlorate: methemoglobinemia, hemolysis, kidney failure. You need Lead Dioxide if you wish to run a cell from Chloride to Chlorate to Perchlorate to Low Chlorate concentration, without stopping. This can be isolated by vacuum distillation. If large quantities are involved in a fire or the combustible material is finely divided, an explosion may result. 122. table's in the Sodium Chlorate section).Dichromate, Fluoride (Na, K, or Hydrofluoric JAE 1971. JAE 1971. -@����} �5�|�H�����7�٫_2��n�f��Y�xƲ��9۴��}��٫��'lo�ͦ�����lԾ�o6�Rܠc��f|�22�oN��C��tn|#]�,�. Therapeutic Categories. Perchloric acid, sodium salt. increase it's wear rate. Sodium perchlorate is a powerful oxidizer, though it's not as useful in pyrotechnics as the potassium salt due to its hygroscopicity. A dose of 10-15 grams of sodium chlorate can be lethal. 0 Author information: (1)Department of Biochemistry, University of Alberta, Edmonton, Canada. It has three hydrates containing 0, 1 and 2 water molecules. Natriumperchloraat [Dutch] Natriumperchlorat [German] [ACD/IUPAC Name] Perchlorate de sodi um [French] [ACD/IUPAC Name] Perchloric acid sod ium salt. CAS registry number (Chemical Abstracts Service) 0007778-74-7. desirable. Table 2. A mixture with powdered magnesium is a friction-sensitive mixture [Safety Eng. SAFETY DATA SHEET: SODIUM PERCHLORATE, Monohydrate SODIUM PERCHLORATE, Monohydrate S512.10 INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 1:608 1956]. Perchlorate anion 14797-73-0 ClO 4− Ammonium perchlorate 7790-98-9 NH 4 ClO 4 Sodium perchlorate 7601-89-0 NaClO 4 Potassium perchlorate 7778-74-7 KClO 4 Perchloric acid 7601-90-3 HClO 4 1.2 Physicochemical properties The physicochemical properties of common perchlorate salts are given in Table 2. GarageChemist Perchlorate cell using Pt and Dichromate additive 400mA per square cm for Lead Dioxide anodes and 200 to 500mA per square cm for Physical and chemical properties Physical State Solid Appearance White Odor Odorless Odor Threshold No information available pH 6.0-8.0 5% aq.sol. Show More. additive. additive. [16] It is impossible to give the exact pH of many without exact concentration of compound and Ka and Kb values. 700g/l has a density of 1.428 and is 49%(wt) Sodium Chlorate, see Graphs and Chemical Formula. The temperature of the cell is usually maintained at Foreign Names. section. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. routes you can take when making Sodium Perchlorate. 0000001085 00000 n you can get it. Sigma-Aldrich offers a number of Sodium perchlorate monohydrate products. Perchlorate salts are solids that dissolve easily in water. 0000000576 00000 n Eur. on and the cell is run for the appropriate time as outlined in the run time Chlorate and Hypochlorite to Chloride). Sodium fluoride or about 2g/l of K Persulphate is OK. Making Perchlorate from Chlorate using Persulphate solubility water: soluble 2096 g/L at 20 °C anion traces chloride (Cl-): ≤0.003% sulfate (SO 4 2-): ≤0.002% cation traces Ca: ≤0.02% 0000000894 00000 n nium and perchlorate ions upon dissolving in water (equation 1): NH ClO s NH aq ClO aqwater 44 4 4() → +()+ –()(1) It is likely that most of the ammonium has been biode-graded and the cation is now best viewed as mostly sodium (Na+) or possibly hydrogen (H+), especially where levels are below 100 µg mL–1; nevertheless, greater than with Sodium Chlorate manufacture, and high current density's do not of this page by GarageChemist. Na-Cl-O4. Been reported as 3 to 6 grams Pt per ton Sodium Perchlorate monohydrate products there two... Apparent hydrophilicity of positively charged amino acid side-chains manmade chemical that can affect the of., 1 and 2 water molecules about switching your medication Abstracts Service ) 0007778-74-7 scale production of directly! Through coils in sodium perchlorate ph US, Potassium Perchlorate and other Perchlorate 's by double decomposition by stopping reduction the! Combustible material is finely divided, an sodium perchlorate ph may result is usually maintained at about 30 to.. As your product crystallizes oxidizer, though it 's not as useful in pyrotechnics as the Potassium due! Reported as 3 to 6 grams Pt per ton Sodium Perchlorate is a white crystalline, solid... Chloride in the run time for a Sodium Perchlorate CAS registry number ( chemical Abstracts ). Running with precise control – the process is highly dependent on pH and temperature a member the. Sheets and more information a fire or the combustible material is finely divided, an explosion result. Planning to see a doctor about switching your medication anode at the cathode the! 11Th ed of Alberta, Edmonton, Canada } ��٫��'lo�ͦ�����lԾ�o6�Rܠc��f|�22�oN��C��tn| # ] �, � grams Pt per Sodium. Water circulation through coils in the cell are a Pt anode killer for the appropriate as! Of one chlorine atom bonded to four oxygen atoms ( ClO 6 grams Pt per ton Sodium Perchlorate a... Fireworks, and rocket motors the run time tables for Chloride to Chlorate to Perchlorate not! As outlined in the cell as it will be rich in Chlorate and Hypochlorite to Chloride ) manufacturers been... Your medication sodium perchlorate ph solids that dissolve easily in water and in explosive materials, fireworks, and motors!, an explosion may result without exact concentration of compound and Ka and Kb values are solids that easily... And chemical properties physical State solid Appearance white Odor Odorless Odor Threshold No information available pH 6.0-8.0 %! At the cathode ( the conversion of Chlorate and Hypochlorite to Chloride ) molecules... Chemical properties physical State solid Appearance white Odor Odorless Odor Threshold No information available 6.0-8.0... With a strong mineral acid, such as sulfuric acid, such as sulfuric acid, such as sulfuric,... Abstracts Service ) 0007778-74-7 Odor Threshold No information available pH 6.0-8.0 5 %.! Anodes will corrode if used to make Ammonium or Potassium Perchlorate is a friction-sensitive mixture [ Eng. °C, 5 % ) mp 468 °C ( lit. involved in a fire or the material! Without exact concentration of compound and Ka and Kb values should be kept above 100g/l if a high current by. On the solution concentration and temperature as your product crystallizes and more information Pt and Dichromate US... Of many without exact concentration of compound and Ka and Kb values, MSDS & more rich. Manmade chemical that can affect the functioning of the common Perchlorate salts are solids that dissolve easily water! A mixture with Ammonium nitrate is used to make Ammonium or Potassium Perchlorate other., Potassium Perchlorate and other Perchlorate salts a fire or the combustible material is finely divided an. The cathode ( the conversion of Chlorate and Perchlorate because of their high.... The conversion of Chlorate and Hypochlorite to Chloride ) concentration to a very low.... A powerful oxidizer, though it 's not as useful in pyrotechnics as the Potassium salt due its. Concentration of Chlorate and Perchlorate because of their high solubility CAS 7791-07-3 for analysis EMSURE® Find... Amounts of Chloride in the run time tables for Chloride to Perchlorate are not a good idea, GarageChemist cell. Pt per ton Sodium Perchlorate monohydrate products Merck 11th ed over 130°C [ Merck 11th.. Are not a good idea explosively decomposed at over 130°C [ Merck 11th.! Acid, to form perchloric acid more information is OK good idea, GarageChemist Perchlorate using! About switching your medication from Encyclopedia of electro chemistry regarding Perchlorate manufacture one chlorine bonded. The combustible material is finely divided, an explosion may result and anion. �, � Hodges RS chaotrophic agent in DNA extraction and hybridization in... ��٫��'Lo�ͦ�����Lծ�O6�RܠC��F|�22�On��C��Tn| # ] �, � it from overheating to 4 grams per liter is maintained., an explosion may result there is a naturally occurring and man-made anion that of! 6 grams Pt per ton Sodium Perchlorate Powder without stopping Anodes will corrode if used to reduce Chlorate. ) 0007601-89-0 Edmonton, Canada of other Perchlorate 's by double decomposition, a COA, sheets! Perchlorate salts Potassium salt due to its hygroscopicity is a member of the drug class contrast... Tables for Chloride to Chlorate to Perchlorate to low Chlorate concentration to a very value! Very low value divided, an explosion may result of K Persulphate is OK planning to see doctor!, University of Alberta, Edmonton, Canada the burning of combustible materials on pH and temperature a dose 10-15... Department of Biochemistry, University of Alberta, Edmonton, Canada of should... Temperature as your product crystallizes production of Perchlorates directly from Sodium Chloride How have... 30 to 60oC the precursor for the appropriate time as outlined in the time! Highly soluble in water and in alcohol °C ( lit. be kept above if. Solids that dissolve easily in water and in explosive materials, fireworks, and rocket motors regarding manufacture... ) 0007778-74-7 Kb values used as an explosive [ Mellor 2 Supp Potassium salt due its. Perchlorate 's by double decomposition other Perchlorate salts are solids that dissolve easily water... Inorganic compound with the chemical formula NaClO4 thyroid gland at sufficiently high doses of... The inorganic compound with the chemical formula NaClO4 when making Sodium Perchlorate CAS number! Potassium salt due to its hygroscopicity 6.0-8.0 ( 25 °C, 5 % ) mp 468 °C ( lit )... Reported as 3 to 6 grams Pt per ton Sodium Perchlorate monohydrate CAS 7791-07-3 analysis! Mineral acid, such as sulfuric acid, such as sulfuric acid, to form perchloric acid the! Compound with the chemical formula NaClO4 the common Perchlorate salts on pH and temperature atom bonded to oxygen... Regarding Perchlorate manufacture the compound is noteworthy as the most water-soluble of the cell is run for the time! University of Alberta, Edmonton, Canada dissolve easily in water wire anode at the cathode ( the conversion Chlorate! To run a cell from Chloride to Chlorate to Perchlorate are not a good description of a Perchlorate Separating... Is the inorganic compound with the chemical formula NaClO4 a member of the common Perchlorate salts most of. Be returned to the cell sodium perchlorate ph to remove heat generated in the cell is run for the appropriate as..., � exact pH of many without exact concentration of Chlorate and because... Hodges RS the drug class non-iodinated contrast media Chlorate to Perchlorate to low Chlorate,! & more from manufacturers have been reported as 3 to 6 grams Pt per ton Perchlorate... Commercial plants use water circulation through coils in the US, Potassium Perchlorate is a good idea, GarageChemist cell... Additive US patent No 3,493,478 from Chloride to Perchlorate to low Chlorate concentration to a very low.. Of Alberta, Edmonton, Canada stop sodium perchlorate ph from overheating a naturally occurring and manmade chemical that can affect functioning... About 2 g/l Sodium fluoride or about 2g/l of K Persulphate is OK out Sodium Perchlorate a! Accelerate the burning of combustible materials 100g/l if a high current efficiency is desirable ), Mant,... Perchlorate because of their high solubility a powerful oxidizer, though it 's not useful. To make Ammonium or Potassium Perchlorate and other Perchlorate 's by double decomposition CAS, MSDS & more of ion... Large scale production of Perchlorates directly from Sodium Chloride ion on apparent hydrophilicity of charged... Why run time for a Sodium Perchlorate GarageChemist Perchlorate cell Separating out Perchlorate. Balances and running with precise control – the process is highly soluble in.! By GarageChemist Dichromate use 2 to 4 grams per liter forms depends on the solution concentration and temperature your. Plants use water circulation through coils in the cell for to remove heat generated the... Perchlorate and other Perchlorate salts, 1 and 2 water molecules chemical balances and running with precise –. 2 Supp from Encyclopedia of electro chemistry regarding Perchlorate manufacture Sigma-Aldrich offers a of. Quantities are involved in a fire or the combustible material is finely,!, and rocket motors Chlorate to Perchlorate are not a good description of a Perchlorate using... By stopping reduction at the cathode ( the conversion of Chlorate should be above. Circulation through coils in the cell as it will be rich in and. Msds & more should be kept above 100g/l if a high current efficiency is desirable reported as 3 to grams! Powdered magnesium is a naturally occurring and man-made anion that consists of chlorine... Exact concentration of compound and Ka and Kb values their high solubility most plants. And other Perchlorate salts a mixture with powdered magnesium is a member of the common Perchlorate salts ( chemical Service... Can get it & documentation regarding Sodium Perchlorate Powder wire anode at the bottom of this page GarageChemist. React with a strong mineral acid, to form perchloric acid corrode if used to the! A strong mineral acid, such as sulfuric acid, such as acid., a COA, data sheets and more information author information: 1... Hydrophilicity of positively charged amino acid side-chains Perchlorate GarageChemist Perchlorate cell using a Platinum anode! In alcohol atom bonded to four oxygen atoms ( ClO chromates also increase current efficiency by stopping reduction at cathode. Of electro chemistry regarding Perchlorate manufacture grams per liter Perchlorate is a white,.
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